Synthesis and Properties of a Novel Diarylethene 1-(2-cyano-1,5-dimethyl-4-pyrryl)- 2-{(2-methyl-4-hydroxymethylphe-nyl)-3-thienyl} Perfluorocyclopentene

نویسندگان

  • Yaming Xue
  • Erting Feng
  • Dandan Xue
  • Renjie Wang
چکیده

An asymmetrical photochromic diarylethene 1-(2cyano-1,5-dimethyl-4-pyrryl)-2-{(2-methyl-4hydroxymethylphe -nyl)-3-thienyl}perfluorocyclopentene (1o) was synthesized and its photochromic properties as well as reaction kinetics were investigated in detail. Upon irradiation with 297 nm UV light, diarylethene 1o exhibited photochromism in solution. Moreover, 1o also exhibited obviously fluorescence switches along with the photochromism. Keywords-diarylethene; photochromic; fluorescence; pyrrole

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منابع مشابه

Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5- (3-methyl)-phenyl-3-thienyl] Perfluorocyclopentene

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Light-driven bending of diarylethene mixed crystals.

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Light-driven bending of diarylethene mixed crystals† †Electronic supplementary information (ESI) available: Synthetic procedures and characterization of 2a, supplementary data, and crystallographic analysis. CCDC 1060727 and 1408475. For ESI and crystallographic data in CIF or other electronic format See DOI: 10.1039/c5sc01994j Click here for additional data file. Click here for additional data file.

Mixed crystals composed of 1,2-bis(2-methyl-5-(p-methoxyphenyl)-3-thienyl)perfluorocyclopentene (1a) and 1,2-bis(5-methyl-2-(p-methoxyphenyl)-4-thiazolyl)perfluorocyclopentene (2a) were prepared, and their photochromic as well as light-driven bending performance was studied to reveal how shape changes of individual molecules cause the bending response. 1a and 2a molecules, having similar geomet...

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تاریخ انتشار 2016